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出生年月 1990年6月 电子邮箱 lijunscdx@163.com
政治面貌 中共党员 电子邮箱 jun_li@zjnu.edu.cn
现在工作单位 浙江师范大学 含氟新材料研究所
教育背景
2012.9-2017.6 四川大学 有机化学理学博士 （导师：冯小明教授，中国科学院院士）
2008.9-2012.6 四川大学 理学学士（化学基地班专业）
工作经历
2022.01-至今 浙江师范大学含氟新材料研究所 “双龙学者”特聘教授
2018.10-2021.10 Heidelberg University (德国) 洪堡学者(博士后)，（导师：A. Stephen K. Hashmi教授）
2017.8-2018.7 Queens University (加拿大) 博士后，（导师： P. Andrew Evans教授）
研究兴趣
1. 金催化、光催化的有机合成方法学以及在天然产物全合成中的应用。
2. Nickel Foam 催化的硝基的氢化还原反应。
3. 手性膦-铱配合物催化的不对称烯丙基化反应。
4. 手性双氮氧/金属配合物催化的不对称催化反应，主要发展了双金属接力催化体系。
科研成果
Jun Li, Hongwei Shi, Shan Zhang, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi* “Switchable Divergent Synthesis in Gold-Catalyzed Difunctionaliza-tions of o-Alkynylbenzenesulfonamides with Aryldiazonium Salts”. Org. Lett., 2021, 23, 7713–7717.
Jun Li, Lili Lin, Bowen Hu, Pengfei Zhou, Tianyu Huang,Xiaohua Liu,* and Xiaoming Feng* “Gold(I)/Chiral N,N′-Dioxide–Nickel(II) Relay Catalysis for Asymmetric Tandem Intermolecular Hydroalkoxylation/Claisen Rearrangement”. Angew. Chem. Int. Ed., 2017, 56, 885–888. (Very Important Paper)
Jun Li, Lili Lin, Bowen Hu, Xiangjin Lian, Gang Wang, Xiaohua Liu,* and Xiaoming Feng* “Bimetallic Gold(I)/Chiral N,N’-Dioxide Nickel(II) Asymmetric Relay Catalysis: Chemo- and Enantioselective Synthesis of Spiroketals and Spiroaminals”. Angew. Chem. Int. Ed., 2016, 55, 6075–6078.
Jun Li, Yuting Liao, Yulong Zhang, Xiaohua Liu, Lili Lin and Xiaoming Feng* “Chiral magnesium(II)-catalyzed asymmetric ring opening of meso-aziridines with primary alcohols”. Chem. Commun., 2014, 50, 6672–6674.
Jun Li, Yunfei Cai, Weiliang Chen, Xiaohua Liu, Lili Lin, and Xiaoming Feng* “Highly Enantioselective Fluorination of Unprotected 3-Substituted Oxindoles: One-Step Synthesis of BMS 204352 (MaxiPost)”.J. Org. Chem., 2012, 77, 9148–9155.
Jun Li, A. Stephen K. Hashmi* “Gold catalysis in total synthesis – state of the art” Review article submitted to Chem. Soc. Rev..
Yunfei Cai, Xiaohua Liu, Jun Li, Weiliang Chen, Wentao Wang, Lili Lin, Xiaoming Feng* “Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on Scandium(III) and a N,N’-Dioxide Ligand”.Chem. Eur. J., 2011, 17, 14916–14921.
Yunfei Cai, Jun Li, Weiliang Chen, Mingsheng Xie, Xiaohua Liu, Lili Lin, and Xiaoming Feng* “Catalytic Asymmetric Sulfenylation of Unprotected 3-Substituted Oxindoles”.Org. Lett., 2012, 14, 2726–2729.
Yali Xu, Yuting Liao, Lili Lin, Yuhang Zhou, Jun Li, Xiaohua Liu, and Xiaoming Feng* “Catalytic Asymmetric Inverse-Electron Demand 1,3-Dipolar Cycloaddition of Isoquinolinium Methylides with Enecarbamates by a Chiral N,N’-Dioxide/Ag(I) Complex”. ACS Catal.,2016, 6, 589–592.
Gang Wang, Xiaohua Liu,* Yushuang Chen, Jian Yang, Jun Li, Lili Lin, and Xiaoming Feng* “Diastereoselective and Enantioselective Alleno-aldol Reaction of Allenoates with Isatins to Synthesis of Carbinol Allenoates Catalyzed by Gold”, ACS Catal.,2016, 6, 2482–2486.
Pengfei Zhou, Yunfei Cai, Xia Zhong, Weiwei Luo, Tengfei Kang, Jun Li, Xiaohua Liu,* Lili Lin, and Xiaoming Feng* “Catalytic Asymmetric Intra- and Intermolecular Haloetherification of Enones: An Efficient Approach to (−)-Centrolobine”. ACS Catal.,2016, 6, 7778–7783.
Kai Fu, Jingchuan Zhang, Lili Lin,* Jun Li, Xiaohua Liu, and Xiaoming Feng*“Chiral N,N′-Dioxide/Lanthanide(III) Complex Catalyzed Asymmetric Bisvinylogous Mukaiyama Aldol Reactions”.Org. Lett., 2017, 19, 332–335.
Bowen Hu, Jun Li, Weidi Cao, Qianchi Lin, Jian Yang, Lili Lin, Xiaohua Liu, Xiaoming Feng* “Asymmetric Synthesis of Fused Bicyclic N,O- and O,O-Acetals via Cascade Reaction by Gold(I)/N,N’-Dioxide-Nickel(II) Bimetallic Relay Catalysis” Adv. Synth. Catal.2018, 360, 2831–2835.
Tapas Adak, Chao Hu, Matthias Rudolph, Jun Li, and A. Stephen K. Hashmi* “Metal-Free, Visible-Light-Enabled Direct C3–H Arylation of Anthranils”. Org. Lett.2020, 22, 5640–5644.
Chao Hu, Kaveh Farshadfar, Martin C. Dietl, Alejandro Cervantes-Reyes, Tao Wang, Tapas Adak, Matthias Rudolph, Frank Rominger, Jun Li, Alireza Ariafard*, and A. Stephen K. Hashmi* “Gold-Catalyzed [5,5]-Rearrangement”. ACS Catal.2021, 11, 6510–6518.
荣誉及奖励
2019年 教育部高等学校科学研究优秀成果奖自然科学一等奖（第九完成人）
2018年 德国洪堡奖学金 2013年 硕士研究生国家奖学金
2016年 四川大学优秀博士 2012-2017 连续5年获得四川大学一等奖学金
2016年 博士研究生国家奖学金 2010年 本科--国家励志奖学金
2014年 硕士研究生国家奖学金 2009年 本科--国家励志奖学金
学术会议
Jun Li; Xiaoming Feng; “Gold(I)/Chiral N,N’-Dioxide-Nickel(II) Asymmetric Relay Catalysis” 20th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS20), Heidelberg, Germany, July 21–25, 2019, P-124, Poster presentations.
Jun Li; Xiaohua Liu; Lili Lin; Xiaoming Feng; “Catalytic Asymmetric Fluorination of Oxindoles and Ring-opening of meso-Aziridines with Primary Alcohols.” 251st ACS National Meeting & Exposition, San Diego, CA, United States, March 13-17, 2016, ORGN-40, Poster presentations.
